2019 - 2020

0351-3820
  Molecular Orbitals in Organic reactions                                                              
FACULTY OF EXACT SCIENCES
Roman DobrovetskyOrnstein - Chemistry110Tue1500-1700 Sem  2
 
 
University credit hours:  2.0

Course description

Structural features

•    Brief introduction of the atomic orbital theory of H atom and the formation of H-H bond using the molecular orbital (MO) theory.
•    Hybridization and MO's of C-H bonds methane, methylene etc.
•    MO's of σ C-C and π C=C bonds
•    Conjugation - Hückel Theory
•    Aromaticity
•    Strained σ Bonds - Cyclopropanes and Cyclobutanes
•    Heteronuclear Bonds, C-X and C=O
•    Hyperconjugation

Chemical Reactions

•    Hard and Soft Acids and Bases; Hard and Soft Nucleophiles and Electrophiles
•    Transition Structures
•    Ionic Reactions
•    Thermal Pericyclic Reactions
•    Photochemical Pericyclic Reactions

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