2019 - 2020 | |||||||||||||||||||||||||||||
0351-3820 | Molecular Orbitals in Organic reactions | ||||||||||||||||||||||||||||
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FACULTY OF EXACT SCIENCES | |||||||||||||||||||||||||||||
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Structural features
• Brief introduction of the atomic orbital theory of H atom and the formation of H-H bond using the molecular orbital (MO) theory.
• Hybridization and MO's of C-H bonds methane, methylene etc.
• MO's of σ C-C and π C=C bonds
• Conjugation - Hückel Theory
• Aromaticity
• Strained σ Bonds - Cyclopropanes and Cyclobutanes
• Heteronuclear Bonds, C-X and C=O
• Hyperconjugation
Chemical Reactions
• Hard and Soft Acids and Bases; Hard and Soft Nucleophiles and Electrophiles
• Transition Structures
• Ionic Reactions
• Thermal Pericyclic Reactions
• Photochemical Pericyclic Reactions