2014 - 2015

0351-1825-01
  Kinetics                                                                                             
FACULTY OF EXACT SCIENCES
Prof. Michael UrbakhWolfson - Engineering0011200-1400 Sem  2
 
 
University credit hours:  2.0

Course description

 

Chemical kinetics: The rate of a chemical reaction, rate laws and rate constants (empirical and integrated), half-life, reactions near equilibrium, radioactivity.
The kinetic theory: Kinetic-molecular theory of gases, distribution of molecular speeds and energies, the collision theory, mean-free-path, effusion and diffusion.
Mechanisms of reaction: Elementary reactions, orders of reaction, reaction mechanism, competing and consecutive reactions, the steady state approximation, uni-molecular reactions and the Lindemann-Hinshelwood mechanism, chain reactions and polymerizations.
The rate constants: Transition state theory, the effect of temperature on reaction rates, activation energy, Aherenius equation, the RRK model for uni-molecular reactions, molecule as collection of harmonic oscillators.
Catalysis: Homogeneous catalysis, heterogeneous catalysis, enzymatic reactions and the Menten-Michaelis mechanism, catalysts and inhibitors, auto-catalytic and oscillatory reactions.

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