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כימיה סופראמולקולרית: ממולקולות בתמיסה למערכות ננו מטריות
Introduction to Supramolecular Chemistry: From Molecules in Solution to Nanometr |
0351-4140 | ||||||||||||||||||||||||||||||||
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מדעים מדויקים | כימיה | |||||||||||||||||||||||||||||||||
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Basic Concepts: Introduction and definition; supramolecular interactions; complementarity; preorganization; chelate effect: macrocyclic effect; template effect; cooperativity and self-assembly.
Characterization of Supramolecular Systems: Association constants, ITC, NMR including diffusion NMR; Mass Spectrometry; Circular dichroism, and Dynamic light scattering (DLS).
Molecular recognition and basic receptor molecules: crown ethers; cryptands; spherands; calixarenes; carcerands; cyclodextrins; cucurbiturils.
Self-Assembly: Coordination systems; hydrogen-bond systems; p-p systems; capsules; rotaxane; catenane; self-assembly of biomolecules
Applications: supramolecular catalysts; reactivity in nanoscale vessels; enzyme mimics; molecular machines; sensor; molecular electronics and magnetic nanopaticles